[2-(Diphenyl­phosphan­yl)benzene­thiol­ato-κ2 P,S](pyridine-2-thiol­ato-κS)(triphenyl­phosphine-κP)palladium(II)

نویسندگان

  • Raúl Ríos-Sanchez
  • Simón Hernández-Ortega
  • David Morales-Morales
  • Alcives Avila-Sorrosa
چکیده

In the title compound, [Pd(C(5)H(4)NS)(C(18)H(14)PS)(C(18)H(15)P)], the Pd(II) atom has a slightly distorted square-planar environment. Two coordination sites are occupied by a P,S-chelating 2-(diphenyl-phosphan-yl)benzene-thiol-ate ligand and the other two by a P atom from a triphenyl-phosphine ligand and an S atom from a pyridine-2-thiol-ate ligand, exhibiting a trans arrangement of the two P-donor atoms. In the crystal structure, weak intra- and inter-molecular C-H⋯π and π-π inter-actions are observed. The pyridyl ring is equally disordered over two positions.

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عنوان ژورنال:

دوره 66  شماره 

صفحات  -

تاریخ انتشار 2010